E-mail a specific user upon one service catalog submission

E-mail a specific user upon one service catalog submission

Greetings,
      We have a use case for one company's termination requests to be sent to a non-IT user so they know to cut access to a specific system. This user is not an SDP user and we will not be spending the money to create him as a technician. 
      We will want this functionality for only one Service Catalog item.

      I thought about making him an approver via Work Flow but that's sort of a crappy workaround and, actually, I may only be able to do that on a company-wide basis.

Suggestions?
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